126236 - Micro-capillary coatings based on spiropyran polymeric brushes for metal ion binding, detection, and release in continuous flow.pdf (17.1 MB)
Micro-capillary coatings based on spiropyran polymeric brushes for metal ion binding, detection, and release in continuous flow
journal contribution
posted on 2023-05-19, 18:28 authored by Dunne, A, Delaney, C, McKeon, A, Nesterenko, PN, Brett PaullBrett Paull, Benito-Lopez, F, Diamond, D, Florea, LMicro-capillaries, capable of light-regulated binding and qualitative detection of divalent metal ions in continuous flow, have been realised through functionalisation with spiropyran photochromic brush-type coatings. Upon irradiation with UV light, the coating switches from the passive non-binding spiropyran form to the active merocyanine form, which binds different divalent metal ions (Zn2+, Co2+, Cu2+, Ni2+, Cd2+), as they pass through the micro-capillary. Furthermore, the merocyanine visible absorbance spectrum changes upon metal ion binding, enabling the ion uptake to be detected optically. Irradiation with white light causes reversion of the merocyanine to the passive spiropyran form, with simultaneous release of the bound metal ion from the micro-capillary coating.
History
Publication title
SensorsVolume
18Issue
4Article number
1083Number
1083Pagination
1-12ISSN
1424-8220Department/School
School of Natural SciencesPublisher
Molecular Diversity Preservation InternationalPlace of publication
Matthaeusstrasse 11, Basel, Switzerland, Ch-4057Rights statement
Copyright 2018 The Authors. Licensed under Creative Commons Attribution 4.0 International (CC BY 4.0) https://creativecommons.org/licenses/by/4.0/Repository Status
- Open