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A common reference material for cadmium isotope studies -- NIST SRM 3108

Citation

Abouchami, W and Galer, SJG and Horner, TJ and Rehkamper, M and Wombacher, F and Xue, Z and Lambelet, M and Gault-Ringold, M and Stirling, CH and Schonbachler, M and Shiel, AE and Weis, D and Holdship, PF, A common reference material for cadmium isotope studies -- NIST SRM 3108, Geostandards and Geoanalytical Research, 37, (1) pp. 5-17. ISSN 1639-4488 (2012) [Refereed Article]

Copyright Statement

Copyright 2012 The Authors. Geostandards and Geoanalytical Research Copyright 2012 International Association of Geoanalysts

DOI: doi:10.1111/j.1751-908X.2012.00175.x

Abstract

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio 114Cd/110Cd for NIST SRM 3108 lies within ∼ 10 ppm Da−1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.

Item Details

Item Type:Refereed Article
Keywords:isotope geochemistry, intercalibration
Research Division:Earth Sciences
Research Group:Geochemistry
Research Field:Isotope Geochemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Earth Sciences
UTAS Author:Gault-Ringold, M (Dr Melanie East)
ID Code:125194
Year Published:2012
Web of Science® Times Cited:52
Deposited By:CRC-Antarctic Climate & Ecosystems
Deposited On:2018-04-06
Last Modified:2018-05-10
Downloads:0

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