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Gold-catalyzed domino cyclization-alkynylation reactions with EBX reagents: new insights into the reaction mechanism
Citation
Ghari, H and Li, Y and Roohzadeh, R and Caramenti, P and Waser, J and Ariafard, A, Gold-catalyzed domino cyclization-alkynylation reactions with EBX reagents: new insights into the reaction mechanism, Dalton Transactions, 46, (36) pp. 12257-12262. ISSN 1477-9226 (2017) [Refereed Article]
Copyright Statement
Copyright 2017 The Royal Society of Chemistry
Abstract
Gold-catalyzed domino processes constitute a useful alternative to C–H functionalization for the synthesis of functionalized (hetero)arenes. Herein, we report computational studies on the gold-catalyzed cyclization alkynylation of keto-allenes with ethynylbenziodoxole (EBX) reagents, which identified a gold(I) picolinate complex as the active catalyst, giving the first mechanistic insights into this transformation.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | catalysis, gold, C–H functionalization, DFT calculation, hypervalent iodine |
| Research Division: | Chemical Sciences |
| Research Group: | Physical chemistry |
| Research Field: | Catalysis and mechanisms of reactions |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Ariafard, A (Associate Professor Alireza Ariafard) |
| ID Code: | 123465 |
| Year Published: | 2017 |
| Web of Science® Times Cited: | 19 |
| Deposited By: | Chemistry |
| Deposited On: | 2018-01-09 |
| Last Modified: | 2022-08-23 |
| Downloads: | 0 |
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