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Condensations of Crotonate Arsonium Ylide with Conjugated Carbonyl Compounds

Citation

Moorhoff, CM, Condensations of Crotonate Arsonium Ylide with Conjugated Carbonyl Compounds, SYNLETT, 1997, (1) pp. 126-128. ISSN 0936-5214 (1997) [Refereed Article]

Abstract

Condensations of methyl 4-(triphenylarsoranylidene)-2-butenoate 1a and conjugated carbonyl compounds give 1,3-cyclohexadiene-1-carboxylates and/or acyclic trienes in superior yields compared to the condensations with the phosphonium analogue 1b. However, the reaction of 1a and ethyl 2-cyano-5-methyl-2,4-hexadienoate 7 gave a mixture of two diastereomeric trans-bisvinylcyclopropanecarboxylates 9.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Organic Chemistry
Research Field:Organic Chemical Synthesis
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Moorhoff, CM (Dr Moorhoff)
ID Code:12040
Year Published:1997
Web of Science® Times Cited:14
Deposited By:Chemistry
Deposited On:1997-08-01
Last Modified:2011-08-15
Downloads:0

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