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Condensations of Crotonate Arsonium Ylide with Conjugated Carbonyl Compounds
Citation
Moorhoff, CM, Condensations of Crotonate Arsonium Ylide with Conjugated Carbonyl Compounds, SYNLETT, 1997, (1) pp. 126-128. ISSN 0936-5214 (1997) [Refereed Article]
Abstract
Condensations of methyl 4-(triphenylarsoranylidene)-2-butenoate 1a and conjugated carbonyl compounds give 1,3-cyclohexadiene-1-carboxylates and/or acyclic trienes in superior yields compared to the condensations with the phosphonium analogue 1b. However, the reaction of 1a and ethyl 2-cyano-5-methyl-2,4-hexadienoate 7 gave a mixture of two diastereomeric trans-bisvinylcyclopropanecarboxylates 9.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Organic Chemistry |
| Research Field: | Organic Chemical Synthesis |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Moorhoff, CM (Dr Moorhoff) |
| ID Code: | 12040 |
| Year Published: | 1997 |
| Web of Science® Times Cited: | 14 |
| Deposited By: | Chemistry |
| Deposited On: | 1997-08-01 |
| Last Modified: | 2011-08-15 |
| Downloads: | 0 |
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