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Condensations of Crotonate Arsonium Ylide with Conjugated Carbonyl Compounds
journal contribution
posted on 2023-05-16, 10:54 authored by Moorhoff, CMCondensations of methyl 4-(triphenylarsoranylidene)-2-butenoate 1a and conjugated carbonyl compounds give 1,3-cyclohexadiene-1-carboxylates and/or acyclic trienes in superior yields compared to the condensations with the phosphonium analogue 1b. However, the reaction of 1a and ethyl 2-cyano-5-methyl-2,4-hexadienoate 7 gave a mixture of two diastereomeric trans-bisvinylcyclopropanecarboxylates 9.
History
Publication title
SYNLETTVolume
1997Pagination
126-128ISSN
0936-5214Department/School
School of Natural SciencesPublisher
VerlagPlace of publication
GermanyRepository Status
- Restricted