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Structure, electronic spectrum and angular-overlap bonding parameters of bis[bis(pyrazol-1-yl)(2-thienyl)methane](nitrato-O,O')nickel(II) nitrate
journal contribution
posted on 2023-05-16, 10:53 authored by Astley, T, Hitchman, MA, Skelton, BW, White, AHThe crystal structure of the complex [Ni(pz2thCH)2(O(O')NO")] NO3 has been determined by X-ray diffraction, where pz and th represent the pyrazolyl and thienyl groups of a potentially tripodal ligand. The thienyl groups are not bound to the metal, which is coordinated to four pyrazolyl groups and a chelating nitrate ion. The electronic 'd-d' transition energies are interpreted in terms of angular-overlap bonding parameters which agree well with those reported for other similar complexes.
History
Publication title
Australian Journal of ChemistryVolume
50Pagination
145-148ISSN
0004-9425Department/School
School of Natural SciencesPublisher
Royal Australian Chemical InstitutePlace of publication
Melbourne, AustraliaRepository Status
- Restricted