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Structure, electronic spectrum and angular-overlap bonding parameters of bis[bis(pyrazol-1-yl)(2-thienyl)methane](nitrato-O,O')nickel(II) nitrate
Citation
Astley, T and Hitchman, MA and Skelton, BW and White, AH, Structure, electronic spectrum and angular-overlap bonding parameters of bis[bis(pyrazol-1-yl)(2-thienyl)methane](nitrato-O,O')nickel(II) nitrate, Australian Journal of Chemistry, 50, (2) pp. 145-148. ISSN 0004-9425 (1997) [Refereed Article]
DOI: doi:10.1071/C96192
Abstract
The crystal structure of the complex [Ni(pz2thCH)2(O(O')NO")] NO3 has been determined by X-ray diffraction, where pz and th represent the pyrazolyl and thienyl groups of a potentially tripodal ligand. The thienyl groups are not bound to the metal, which is coordinated to four pyrazolyl groups and a chelating nitrate ion. The electronic 'd-d' transition energies are interpreted in terms of angular-overlap bonding parameters which agree well with those reported for other similar complexes.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic Chemistry |
| Research Field: | Transition Metal Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| UTAS Author: | Astley, T (Mr Timothy Astley) |
| UTAS Author: | Hitchman, MA (Dr Michael Hitchman) |
| ID Code: | 11964 |
| Year Published: | 1997 |
| Web of Science® Times Cited: | 12 |
| Deposited By: | Chemistry |
| Deposited On: | 1997-08-01 |
| Last Modified: | 2011-08-15 |
| Downloads: | 0 |
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