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Structure, electronic spectrum and angular-overlap bonding parameters of bis[bis(pyrazol-1-yl)(2-thienyl)methane](nitrato-O,O')nickel(II) nitrate

Citation

Astley, T and Hitchman, MA and Skelton, BW and White, AH, Structure, electronic spectrum and angular-overlap bonding parameters of bis[bis(pyrazol-1-yl)(2-thienyl)methane](nitrato-O,O')nickel(II) nitrate, Australian Journal of Chemistry, 50, (2) pp. 145-148. ISSN 0004-9425 (1997) [Refereed Article]

DOI: doi:10.1071/C96192

Abstract

The crystal structure of the complex [Ni(pz2thCH)2(O(O')NO")] NO3 has been determined by X-ray diffraction, where pz and th represent the pyrazolyl and thienyl groups of a potentially tripodal ligand. The thienyl groups are not bound to the metal, which is coordinated to four pyrazolyl groups and a chelating nitrate ion. The electronic 'd-d' transition energies are interpreted in terms of angular-overlap bonding parameters which agree well with those reported for other similar complexes.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic Chemistry
Research Field:Transition Metal Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Astley, T (Mr Timothy Astley)
Author:Hitchman, MA (Dr Michael Hitchman)
ID Code:11964
Year Published:1997
Web of Science® Times Cited:12
Deposited By:Chemistry
Deposited On:1997-08-01
Last Modified:2011-08-15
Downloads:0

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