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(2,2'-bipyridyl-N,N')dibromopalladium(II)

Citation

Smeets, WJJ and Spek, AL and Hoare, JL and Canty, AJ and Hovestad, N and Van Koten, G, (2,2'-bipyridyl-N,N')dibromopalladium(II), Acta Crystallographica. Section C: Crystal Structure Communications, 53, (8) pp. 1045-1047. ISSN 0108-2701 (1997) [Refereed Article]

DOI: doi:10.1107/S0108270197004149

Abstract

The title complex, [PdBr2(C10H8N2)], has square-planar geometry for palladium with Pd - N 2.047 (5) and Pd - Br 2.4102 (9) Å. The mean planes of the coordinated pyridine groups form a dihedral angle of 1.7(3)○ with the coordination square plane; the parallel complexes stack with an interplanar spacing of 3.41 (1) Å and a PP ⋯Pd separation of 5.246 (1) Å to form a chain structure as reported for isomorphous PtI2(bipy) (where bipy is 2,2′-bipyridyl, C10H8N2). The structure differs from those found for related chain structures in the 'red' form of PtCl2(bipy) and in PdCl2(bipy) which is isomorphous with the 'yellow' form of PtCl2(bipy).

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Hoare, JL (Mr Jason Lancelot Hoare)
Author:Canty, AJ (Professor Allan Canty)
ID Code:11885
Year Published:1997
Web of Science® Times Cited:15
Deposited By:Chemistry
Deposited On:1997-08-01
Last Modified:2011-08-12
Downloads:0

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