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A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates

Citation

Noor, A and Li, J and Khairallah, GN and Li, Z and Ghari, H and Canty, AJ and Ariafard, A and Donnelly, PS and O'Hair, RAJ, A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates, Chemical Communications, 53, (27) pp. 3854-3857. ISSN 1359-7345 (2017) [Refereed Article]

Copyright Statement

The Royal Society of Chemistry 2017

DOI: doi:10.1039/c7cc00865a

Abstract

A new palladium mediated "one pot" synthesis of thioamides from aromatic carboxylic acids (ArCO2H + RNCS → ArC(S)NHR + CO2) was discovered by gas-phase experiments and theoretical studies. Palladium-mediated decarboxylation of aromatic carboxylic acids followed by addition of substituted isothiocyanates leads to the corresponding thioamide derivatives.

Item Details

Item Type:Refereed Article
Keywords:metal mediated synthesis, thioamide synthesis, organopalladium
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Canty, AJ (Professor Allan Canty)
ID Code:116536
Year Published:2017
Web of Science® Times Cited:1
Deposited By:Chemistry
Deposited On:2017-05-12
Last Modified:2017-07-21
Downloads:0

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