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A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates
Citation
Noor, A and Li, J and Khairallah, GN and Li, Z and Ghari, H and Canty, AJ and Ariafard, A and Donnelly, PS and O'Hair, RAJ, A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates, Chemical Communications, 53, (27) pp. 3854-3857. ISSN 1359-7345 (2017) [Refereed Article]
Copyright Statement
© The Royal Society of Chemistry 2017
Abstract
A new palladium mediated "one pot" synthesis of thioamides from aromatic carboxylic acids (ArCO2H + RNCS → ArC(S)NHR + CO2) was discovered by gas-phase experiments and theoretical studies. Palladium-mediated decarboxylation of aromatic carboxylic acids followed by addition of substituted isothiocyanates leads to the corresponding thioamide derivatives.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | metal mediated synthesis, thioamide synthesis, organopalladium |
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic chemistry |
| Research Field: | Organometallic chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Canty, AJ (Professor Allan Canty) |
| UTAS Author: | Ariafard, A (Associate Professor Alireza Ariafard) |
| ID Code: | 116536 |
| Year Published: | 2017 |
| Web of Science® Times Cited: | 19 |
| Deposited By: | Chemistry |
| Deposited On: | 2017-05-12 |
| Last Modified: | 2022-08-22 |
| Downloads: | 0 |
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