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Carbon-Carbon Bond-Forming Reductive Elimination from Isolated Nickel(III) Complexes


Bour, JR and Camasso, NM and Meucci, EA and Kampf, JW and Canty, AJ and Sanford, MS, Carbon-Carbon Bond-Forming Reductive Elimination from Isolated Nickel(III) Complexes, Journal of the American Chemical Society, 138, (49) pp. 16105-16111. ISSN 0002-7863 (2016) [Refereed Article]

Copyright Statement

Copyright 2016 American Chemical Society

DOI: doi:10.1021/jacs.6b10350


This manuscript describes the design, synthesis, characterization, and reactivity studies of organometallic NiIII complexes of general structure TpNiIII(R)(R1) (Tp = tris(pyrazolyl)borate). With appropriate selection of the R and R1 ligands, the complexes are stable at room temperature and can be characterized by cyclic voltammetry, EPR spectroscopy, and X-ray crystallography. Upon heating, many of these NiIII compounds undergo C(sp2)C(sp2) or C(sp3)C(sp2) bond-forming reactions that are challenging at lower oxidation states of nickel.

Item Details

Item Type:Refereed Article
Keywords:p, alladium, palladium-oxygen, DFT, nucleophilic attack
Research Division:Chemical Sciences
Research Group:Inorganic chemistry
Research Field:Organometallic chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Canty, AJ (Professor Allan Canty)
ID Code:114704
Year Published:2016
Web of Science® Times Cited:79
Deposited By:Chemistry
Deposited On:2017-02-24
Last Modified:2022-08-19

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