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ent-Labdane Diterpenoids from Dodonaea viscosa


Olivier, WJ and Kilah, NL and Horne, J and Bissember, AC and Smith, JA, ent-Labdane Diterpenoids from Dodonaea viscosa, Journal of Natural Products, 79, (12) pp. 3117-3126. ISSN 0163-3864 (2016) [Refereed Article]

Copyright Statement

© 2016 American Chemical Society and American Society of Pharmacognosy

DOI: doi:10.1021/acs.jnatprod.6b00858


Seven new and two known ent-labdane diterpenoids have been isolated from a single plant specimen of Dodonaea viscosa ssp. spatulata, found in Tasmania, Australia. Prior to this study, only seven different labdane diterpenoids had been isolated from D. viscosa. The structures of the natural products were assigned via 1D and 2D NMR spectroscopy and other standard spectroscopic methods. The absolute configuration of three ent-labdane diterpenoids was determined by single-crystal X-ray crystallography of synthetic derivatives. Significantly, the results of this study suggest that the absolute configuration of some known labdane diterpenoids may have been misassigned.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Organic chemistry
Research Field:Organic chemical synthesis
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Olivier, WJ (Mr Wesley Olivier)
UTAS Author:Kilah, NL (Dr Nathan Kilah)
UTAS Author:Horne, J (Dr James Horne)
UTAS Author:Bissember, AC (Associate Professor Alex Bissember)
UTAS Author:Smith, JA (Associate Professor Jason Smith)
ID Code:113469
Year Published:2016
Web of Science® Times Cited:9
Deposited By:Chemistry
Deposited On:2017-01-04
Last Modified:2017-10-25

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