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Individual particle morphology, coatings, and impurities of black carbon aerosols in Antarctic ice and tropical rainfall
Citation
Ellis, A and Edwards, R and Saunders, M and Chakrabarty, RK and Subramanian, R and Timms, NE and van Riessen, A and Smith, AM and Lambrinidis, D and Nunes, LJ and Vallelonga, P and Goodwin, ID and Moy, AD and Curran, MAJ and van Ommen, TD, Individual particle morphology, coatings, and impurities of black carbon aerosols in Antarctic ice and tropical rainfall, Geophysical Research Letters, 43, (22) pp. 11875-11883. ISSN 0094-8276 (2016) [Refereed Article]
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Copyright Statement
©2016. American Geophysical Union. All Rights Reserved.
Abstract
Black carbon (BC) aerosols are a large source of climate warming, impact atmospheric chemistry, and are implicated in large-scale changes in atmospheric circulation. Inventories of BC emissions suggest significant changes in the global BC aerosol distribution due to human activity. However, little is known regarding BC's atmospheric distribution or aged particle characteristics before the twentieth century. Here we investigate the prevalence and structural properties of BC particles in Antarctic ice cores from 1759, 1838, and 1930 Common Era (C.E.) using transmission electron microscopy and energy-dispersive X-ray spectroscopy. The study revealed an unexpected diversity in particle morphology, insoluble coatings, and association with metals. In addition to conventionally occurring BC aggregates, we observed single BC monomers, complex aggregates with internally, and externally mixed metal and mineral impurities, tar balls, and organonitrogen coatings. The results of the study show BC particles in the remote Antarctic atmosphere exhibit complexity that is unaccounted for in atmospheric models of BC.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | black carbon, aerosols, ice cores, Antarctic ice |
| Research Division: | Earth Sciences |
| Research Group: | Atmospheric Sciences |
| Research Field: | Climate Change Processes |
| Objective Division: | Environment |
| Objective Group: | Climate and Climate Change |
| Objective Field: | Climate and Climate Change not elsewhere classified |
| UTAS Author: | Moy, AD (Dr Andrew Moy) |
| UTAS Author: | Curran, MAJ (Dr Mark Curran) |
| UTAS Author: | van Ommen, TD (Dr Tas van Ommen) |
| ID Code: | 113238 |
| Year Published: | 2016 |
| Deposited By: | CRC-Antarctic Climate & Ecosystems |
| Deposited On: | 2016-12-16 |
| Last Modified: | 2017-10-30 |
| Downloads: | 107 View Download Statistics |
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