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Visible light dye-photosensitised oxidation of pyrroles using a simple LED photoreactor
Citation
Howard, JK and Rihak, KJ and Hyland, CJT and Bissember, AC and Smith, JA, Visible light dye-photosensitised oxidation of pyrroles using a simple LED photoreactor, Organic and Biomolecular Chemistry, 14, (37) pp. 8873-8880. ISSN 1477-0520 (2016) [Refereed Article]
Copyright Statement
Copyright 2016 The Royal Society of Chemistry
Abstract
The photooxidation of pyrrole is typically low yielding due to the absorbance of ultraviolet light, which leads to uncontrolled polymerisation and decomposition. Presented herein is the development of a simple and cost-effective photoreactor utilising Light Emitting Diodes (LEDs) as the light source, and its application to the dye-sensitised oxidation of a range of pyrroles to give corresponding 3-pyrrolin-2-ones. The broader applicability of this approach to the generation of 1O2 is also explored.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | atom-economical, oxidation, LED |
| Research Division: | Chemical Sciences |
| Research Group: | Organic Chemistry |
| Research Field: | Organic Chemical Synthesis |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Howard, JK (Mr James Howard) |
| Author: | Rihak, KJ (Mr Kieran Rihak) |
| Author: | Hyland, CJT (Dr Chris Hyland) |
| Author: | Bissember, AC (Dr Alex Bissember) |
| Author: | Smith, JA (Associate Professor Jason Smith) |
| ID Code: | 111726 |
| Year Published: | 2016 |
| Web of Science® Times Cited: | 2 |
| Deposited By: | Chemistry |
| Deposited On: | 2016-10-03 |
| Last Modified: | 2018-03-14 |
| Downloads: | 0 |
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