Giuliani, A and Phillips, D and Kamenetsky, VS and Goemann, K, Constraints on kimberlite ascent mechanisms revealed by phlogopite compositions in kimberlites and mantle xenoliths, Lithos, 240-243 pp. 189-201. ISSN 0024-4937 (2016) [Refereed Article]
Copyright 2015 Elsevier B.V.
Kimberlite magmas are of economic and scientific importance because they represent the major host to diamonds and are probably the deepest magmas from continental regions. In addition, kimberlite magmas transport abundant mantle and crustal xenoliths, thus providing fundamental information on the composition of the sub-continental lithosphere. Despite their importance, the composition and ascent mechanism(s) of kimberlite melts remain poorly constrained. Phlogopite is one of the few minerals that preserves a history of fluid migration and magmatism in the mantle and crust and is therefore an invaluable petrogenetic indicator of kimberlite magma evolution.
Here we present major and trace element compositional data for phlogopite from the Bultfontein kimberlite (Kimberley, South Africa; i.e. the kimberlite type-locality) and from entrained mantle xenoliths. Phlogopite macrocrysts (~ > 0.3–0.5 mm) and microcrysts (between ~ 0.1 and 0.3 mm) in the Bultfontein kimberlite display concentric compositional zoning patterns. The cores of these phlogopite grains exhibit compositions typical of phlogopite contained in peridotite mantle xenoliths. However, the rims of some grains show compositions analogous to kimberlite groundmass phlogopite (i.e. high Ti, Al and Ba; low Cr), whereas other rims and intermediate zones (between cores and rims) exhibit unusually elevated Cr and lower Al and Ba concentrations. The latter compositions are indistinguishable from matrix phlogopite in polymict breccia xenoliths (considered to represent failed kimberlite intrusions) and from Ti-rich overgrowth rims on phlogopite in other mantle xenoliths. Consequently, it is likely that these phlogopite grains crystallized from kimberlite melts and that the high Ti-Cr zones originated from earlier kimberlite melts at mantle depths.
We postulate that successive pulses of ascending kimberlite magma progressively metasomatised the conduit along which later kimberlite pulses ascended, producing progressively decreasing interaction with the surrounding mantle rocks. In our view, these processes represent the fundamental mechanism of kimberlite magma ascent. Our study also indicates that, in addition to xenoliths/xenocrysts and magmatic phases, kimberlite rocks incorporate material crystallized at various mantle depths by previous kimberlite intrusions (mantle-derived ‘antecrysts’).
|Item Type:||Refereed Article|
|Keywords:||kimberlite, phlogopite, zoning, magma ascent, mantle xenoliths, Kimberley|
|Research Division:||Earth Sciences|
|Research Field:||Igneous and Metamorphic Petrology|
|Objective Division:||Expanding Knowledge|
|Objective Group:||Expanding Knowledge|
|Objective Field:||Expanding Knowledge in the Earth Sciences|
|Author:||Kamenetsky, VS (Professor Vadim Kamenetsky)|
|Author:||Goemann, K (Dr Karsten Goemann)|
|Funding Support:||Australian Research Council (DP1092823)|
|Web of Science® Times Cited:||17|
|Deposited By:||Earth Sciences|
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