eCite Digital Repository
Oxidative ring-opening of ferrocenylcyclopropylamines to N-ferrocenylmethyl β-hydroxyamides
Citation
Gee, YS and Goertz, NJM and Gardiner, MG and Hyland, CJT, Oxidative ring-opening of ferrocenylcyclopropylamines to N-ferrocenylmethyl β-hydroxyamides, Organic and Biomolecular Chemistry, 14, (8) pp. 2498-2503. ISSN 1477-0520 (2016) [Refereed Article]
Copyright Statement
Copyright 2016 The Royal Society of Chemistry
Abstract
The in situ reduction of ferrocenyl cyclopropylimines to the corresponding amines triggers a facile oxidative ring-opening to yield the formal four-electron oxidation products: N-ferrocenylmethyl β-hydroxyamides. This process is believed to proceed via generation of a ferrocinium ion in the presence of air, leading to facile formation of a distonic radical cation that is ultimately trapped by oxygen.
DOI for erratum: 10.1039/c6ob90061e
Item Details
Item Type: | Refereed Article |
---|---|
Keywords: | catalysis, organometallic |
Research Division: | Chemical Sciences |
Research Group: | Inorganic chemistry |
Research Field: | Transition metal chemistry |
Objective Division: | Manufacturing |
Objective Group: | Industrial chemicals and related products |
Objective Field: | Organic industrial chemicals (excl. resins, rubber and plastics) |
UTAS Author: | Gardiner, MG (Associate Professor Michael Gardiner) |
ID Code: | 107800 |
Year Published: | 2016 |
Web of Science® Times Cited: | 5 |
Deposited By: | Chemistry |
Deposited On: | 2016-03-24 |
Last Modified: | 2018-03-14 |
Downloads: | 0 |
Repository Staff Only: item control page