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Investigation of adsorption of phenols on detonation nanodiamonds using liquid column chromatography


Lanin, SN and Rychkova, SA and Vinogradov, AE and Lanina, KS and Obrezkov, ON and Nesterenko, PN, Investigation of adsorption of phenols on detonation nanodiamonds using liquid column chromatography, Diamond and Related Materials, 64 pp. 49-56. ISSN 0925-9635 (2016) [Refereed Article]

Copyright Statement

© 2016 Elsevier

DOI: doi:10.1016/j.diamond.2016.01.005


Adsorption of phenols on microdisperse sintered detonation nanodiamond (MSDN) from water–acetonitrile solutions was investigated using high performance liquid chromatography (HPLC). Parabolic dependence between retention and organic solvent content in mobile phase was observed. The influence of physicochemical characteristic solutes including molecular volume (V), dipole moment (μ), hydrophobicity (logP), polarizability (α) and molecular refractivity (MR)) of phenols on their adsorption from water–acetonitrile solutions was investigated. Single- and multi-parameter correlations between retention factor and various physicochemical characteristics of sorbates were obtained. The effect of column temperature on adsorption of phenols on UDD was investigated. The changes in ΔH and ΔS for competitive adsorption of the test sorbates were determined.

Item Details

Item Type:Refereed Article
Keywords:ultradispersed diamond, adsorption, concentrating, phenols, high performance liquid chromatography
Research Division:Chemical Sciences
Research Group:Analytical chemistry
Research Field:Separation science
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Nesterenko, PN (Professor Pavel Nesterenko)
ID Code:106836
Year Published:2016
Funding Support:Australian Research Council (DP150102608)
Web of Science® Times Cited:12
Deposited By:Chemistry
Deposited On:2016-02-23
Last Modified:2017-10-30

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