eCite Digital Repository
Synthesis and x-ray structural studies of substituted 2,3,4,5-tetrahydro-1H-3-benzazonine and a 1,2,3,5-tetrahydro-4,3-benzoxazonine
Citation
Bailey, TS and Bremner, JB and Skelton, BW and White, AH, Synthesis and x-ray structural studies of substituted 2,3,4,5-tetrahydro-1H-3-benzazonine and a 1,2,3,5-tetrahydro-4,3-benzoxazonine, Molecules, 20, (1) pp. 487-502. ISSN 1420-3049 (2015) [Refereed Article]
 | PDF 3Mb |
Copyright Statement
© 2014 the authors Licensed under Creative Commons Attribution 4.0 International (CC BY 4.0) https://creativecommons.org/licenses/by/4.0/
DOI: doi:10.3390/molecules20010487
Abstract
Using a common 1-(1-phenylethenyl)-1,2,3,4-tetrahydroisoquinoline precursor to the required ylide or N-oxide intermediate, the Stevens [2,3] and analogous Meisenheimer [2,3] sigmatropic rearrangements have been applied to afford concise syntheses of phenyl -substituted representatives of each of the reduced 1H-3-benzazonine and 4,3-benzoxazonine systems, respectively. Single crystal X-ray structure determinations were employed to define the conformational characteristics for each ring type.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | large rings, x-ray crystal structures, benzazonine, benzoxazonine |
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic chemistry |
| Research Field: | Transition metal chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Bailey, TS (Mr Timothy Samuel Bailey) |
| UTAS Author: | Bremner, JB (Professor John Bremner) |
| ID Code: | 106290 |
| Year Published: | 2015 |
| Web of Science® Times Cited: | 1 |
| Deposited By: | Chemistry |
| Deposited On: | 2016-02-04 |
| Last Modified: | 2016-08-25 |
| Downloads: | 125 View Download Statistics |
Repository Staff Only: item control page