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σ-Alkenyl endo-palladacycle formation via regiospecific functionalisation of an unreactive NHC-tethered C(sp2)–H bond

journal contribution
posted on 2023-05-18, 16:02 authored by Chapman, MR, Pask, CM, Alireza AriafardAlireza Ariafard, Willans, CE
An unusual cyclometallation reaction at palladium is described, which proceeds via C–H functionalisation of a vinylic C(sp2)–H bond tethered to an NHC ligand. The energetic balance between palladacycle formation and bis-NHC complexation has been found to be very subtle.

History

Publication title

Chemical Communications

Volume

51

Issue

25

Pagination

5513-5515

ISSN

1359-7345

Department/School

School of Natural Sciences

Publisher

Royal Soc Chemistry

Place of publication

Thomas Graham House, Science Park, Milton Rd, Cambridge, England, Cambs, Cb4 0Wf

Rights statement

Copyright 2015 The Royal Society of Chemistry

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  • Restricted

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Expanding knowledge in the chemical sciences

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