eCite Digital Repository

Hydrodechlorination of chlorobenzene on Ni and Ni-Pd catalysts modified by heteropolycompounds of the Keggin type

Citation

Navalikhina, MD and Kavalerskaya, NE and Lokteva, ES and Peristyy, AA and Golubina, EV and Lunin, VV, Hydrodechlorination of chlorobenzene on Ni and Ni-Pd catalysts modified by heteropolycompounds of the Keggin type, Russian Journal of Physical Chemistry A, 86, (11) pp. 1669-1675. ISSN 0036-0244 (2013) [Refereed Article]

Copyright Statement

Copyright 2012 Pleiades Publishing, Ltd.

DOI: doi:10.1134/S0036024412110192

Abstract

Ni and Ni-Pd catalysts modified by heteropolycompounds (HPCs) of the Keggin type are shown to be active in the gas-phase hydrodechlorination of chlorobenzene. The dispersion of the metal and the degree of its interaction with the support are found to change upon the addition of HPCs. The activity of the modified catalysts changes depending on the HPCs’ composition, benzene and cyclohexane being present in the products of hydrodechlorination. The addition of Pd as a second active metal is found to change both the activity and selectivity of the produced catalysts (with benzene as the sole product).

Item Details

Item Type:Refereed Article
Keywords:Ni and Ni–Pd catalysts, hydrodechlorination, chlorobenzene, modification of support, heteropolycompound
Research Division:Chemical Sciences
Research Group:Physical Chemistry (incl. Structural)
Research Field:Catalysis and Mechanisms of Reactions
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Peristyy, AA (Dr Anton Peristyy)
ID Code:104587
Year Published:2013
Web of Science® Times Cited:1
Deposited By:Chemistry
Deposited On:2015-11-16
Last Modified:2017-11-02
Downloads:0

Repository Staff Only: item control page